Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine).
CuF(2)(H(2)O)(2)(3-chloropyridine) possesses a five-coordinate Cu(2+) center with a slightly distorted trigonal bypyramidal coordination geometry. Strong intermolecular F···H-O hydrogen bonds enable the formation of 2D layers and provide the primary magnetic exchange path that leads to the stabiliza...
| Main Authors: | , , , , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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