The effect of chain stiffness on the phase behaviour of isolated homopolymers

We have studied the thermodynamics of isolated homopolymer chains of varying stiffness using a lattice model. A complex phase behaviour is found: phases include chain-folded "crystalline" structures, the disordered globule and the coil. It is found, in agreement with recent theoretical cal...

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Bibliographic Details
Main Authors: Doye, J, Sear, R, Frenkel, D
Format: Journal article
Language:English
Published: 1998