Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L-2)}(+) Fragments
Rhodium(III) dihydrido complexes [Rh(L2)(H)2(acetone) ][BArF4] (ArF = C6H 3(CF3)2) containing the potentially hemilabile ligands L2 = 9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene (Xantphos) and [Ph2P(CH2)2]2O (POP′) have been prepared from their corresponding norbornadiene rhodium(I) precursors....
| Hauptverfasser: | , , , , , , |
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| Format: | Journal article |
| Sprache: | English |
| Veröffentlicht: |
2010
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