Structural snapshots in reversible phosphinidene transfer: synthetic, structural, and reaction chemistry of a Sn═P double bond
The reaction of amido-substituted stannylenes with phospha-Wittig reagents (Me3PPR) results in release of hexamethyldisilazane and tethering of the resulting −CH2PMe2PR fragment to the tin center to give P-donor stabilized stannylenes featuring four-membered Sn,C,P,P heterocycles. Through systematic...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2022
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