Structural snapshots in reversible phosphinidene transfer: synthetic, structural, and reaction chemistry of a Sn═P double bond

The reaction of amido-substituted stannylenes with phospha-Wittig reagents (Me3PPR) results in release of hexamethyldisilazane and tethering of the resulting −CH2PMe2PR fragment to the tin center to give P-donor stabilized stannylenes featuring four-membered Sn,C,P,P heterocycles. Through systematic...

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Detalhes bibliográficos
Principais autores: Fischer, M, Roy, MMD, Wales, LL, Ellwanger, MA, Heilmann, A, Aldridge, S
Formato: Journal article
Idioma:English
Publicado em: American Chemical Society 2022