Amino acid functionalisation using the 2-phosphaethynolate anion. A facile route to (phosphanyl)carbonyl-amino acids

We describe the reactivity of the 2-phosphaethynolate anion (PCO(-)) towards enantiomerically pure α-amino acids (AAs) resulting in the formation of novel salts of phosphinecarboxamides bearing chiral functionalities. These transformations occurred quantitatively with all but one of the amino acids...

Ausführliche Beschreibung

Bibliographische Detailangaben
Hauptverfasser: Faria, E, Jupp, A, Goicoechea, J
Format: Journal article
Sprache:English
Veröffentlicht: Royal Society of Chemistry 2017