DIMER AND TRIMER CALIX[4]ARENES CONTAINING MULTIPLE METALLOCENE REDOX-ACTIVE CENTERS - SINGLE-CRYSTAL X-RAY STRUCTURE OF A BIS(FERROCENE)-BIS(P-TERT-BUTYLCALIX[4]-ARENE) HYDROPHOBIC HOST MOLECULE

The condensation of 1,1′-bis(chlorocarbonyl)ferrocene (1) and 1,1′-bis(chlorocarbonyl)ruthenocene (2) with p-t-butylcalix[4]arene gave the respective new redox-active metallocene-calix[4]arene dimers (3) and (4). An X-ray diffraction study of (3) shows the two calix[4]arenes to be in cone conformati...

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Bibliographic Details
Main Authors: Beer, P, Keefe, A, Slawin, A, Williams, D
Format: Journal article
Language:English
Published: 1990