Control of stereogenic oxygen in a helically chiral oxonium ion

The control of tetrahedral carbon stereocentres remains a focus of modern synthetic chemistry and is enabled by their configurational stability. By contrast, trisubstituted nitrogen1, phosphorus2 and sulfur compounds3 undergo pyramidal inversion, a fundamental and well-recognized stereochemical phen...

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Bibliographic Details
Main Authors: Smith, O, Popescu, MV, Hindson, MJ, Paton, RS, Burton, JW, Smith, MD
Format: Journal article
Language:English
Published: Springer Nature 2023