Group 5 imido complexes supported by diamido-pyridine ligands: Aryloxide, amide, benzamidinate, alkyl, and cyclopentadienyl derivatives
A family of new organometallic and coordination group 5 compounds supported by an imido-diamido-pyridine ligand set are reported. Reaction of [M(NR)Cl(κ3-N2Npy)(py)] (M = Nb, R = tBu 1; M = Ta, R = tBu 2 or Ar 3, where N2Npy = MeC(2-C5H4N)(CH2NSiMe3)2 and Ar = 2,6-C6H3iPr2) with LiOAr or LiPhC(NSiMe...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2001
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