C-C and C-N coupling reactions of an imidotitanium complex with isocyanides
Reaction of the imidotitanium complex [(k3-N2Npy)Ti(=NtBu)(py)] (1) [N2Npy = (2-C5H4N)C(Me)(CH2NSiMe3) 2] with 2,6-xylylisocyanide led to double insertion of the isocyanide into the imidotitanium bond and yielded the four-membered titanacycle [(k3-N2Npy)Ti-{N(tBu)C(=N-2,6-Me2C 6H3)C(=N-2,6-C6H3Me2)}...
| Main Authors: | , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2000
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