Structural, electronic, and magnetic properties of quasi-1D quantum magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6(-), SbF6(-)) exhibiting Ni-FHF-Ni and Ni-pyz-Ni spin interactions.

Structural, electronic, and magnetic properties of quasi-1D quantum magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6(-), SbF6(-)) exhibiting Ni-FHF-Ni and Ni-pyz-Ni spin interactions.

[Ni(HF(2))(pyz)(2)]X {pyz = pyrazine; X = PF(6)(-) (1), SbF(6)(-) (2)} were structurally characterized by synchrotron X-ray powder diffraction and found to possess axially compressed NiN(4)F(2) octahedra. At 298 K, 1 is monoclinic (C2/c) with unit cell parameters, a = 9.9481(3), b = 9.9421(3), c = 1...

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Bibliografske podrobnosti
Main Authors: Manson, J, Lapidus, S, Stephens, P, Peterson, P, Carreiro, K, Southerland, H, Lancaster, T, Blundell, S, Steele, A, Goddard, P, Pratt, F, Singleton, J, Kohama, Y, McDonald, R, Del Sesto, R, Smith, N, Bendix, J, Zvyagin, SA, Kang, J, Lee, C, Whangbo, M, Zapf, V, Plonczak, A
Format: Journal article
Jezik:English
Izdano: 2011

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