THE ASYMMETRIC-SYNTHESIS OF BETA-LACTAMS - STEREOCONTROLLED ASYMMETRIC TANDEM MICHAEL ADDITIONS AND SUBSEQUENT ALKYLATIONS OF E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH - CHME]

THE ASYMMETRIC-SYNTHESIS OF BETA-LACTAMS - STEREOCONTROLLED ASYMMETRIC TANDEM MICHAEL ADDITIONS AND SUBSEQUENT ALKYLATIONS OF E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH - CHME]

Michael addition of methyllithium to the E-crotonyl complex (RS)-[η5-C5H5)Fe(CO)-(PPh3 )COCHCHMe] followed by trapping of the resultant enolate with methyl iodide gives (RS)-[(η5-C5H5)Fe(CO)(PPh3 )COCH(Me)CHMe2] (d.e. > 100:1), also generated by treatment of (RS)-[(η5-C5H5)Fe(CO)(PPh3 )COCH2C...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون:	Davies, S, Dordorhedgecock, I, Sutton, K, Walker, J, Jones, R, Prout, K
التنسيق:	Journal article
اللغة:	English
منشور في:	1986

مواد مشابهة

CHIRAL DIENOLATES - FORMATION AND STEREOSELECTIVE ALPHA-ALKYLATION OF THE LITHIUM DIENOLATE DERIVED FROM (Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-(Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME]
حسب: Davies, S, وآخرون
منشور في: (1987)

STEREOCHEMICAL CONTROL AND MECHANISTIC ASPECTS OF THE ALKYLATION OF [(ETA-5-C5H5)FE(PPH3,PPH2NET2)(CO)(COCH(ME)ET)]-LI+ - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(PPH3)(CO)(COCH(ME)ET)]
حسب: Baird, G, وآخرون
منشور في: (1983)

FRAGMENTATION OF (ETA-5-C5H5)FE(CO)(PPH3)(COCH2COR) COMPLEXES TO THE CATION [(ETA-5-C5H5)FE(CO)2(PPH3)]+
حسب: Davies, S, وآخرون
منشور في: (1983)

PREPARATION AND REACTIVITY OF THE ANION "[(ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]LI
حسب: Aktogu, N, وآخرون
منشور في: (1982)

DETERMINATION OF THE ABSOLUTE-CONFIGURATION AND OPTICAL PURITY OF [(ETA-5-C5H5)FE(CO)(PPH3)COME] - X-RAY CRYSTAL-STRUCTURE OF (R)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2CH2O[(R)-MENTHYL]]
حسب: Davies, S, وآخرون
منشور في: (1986)

CHIRAL DISCRIMINATION IN THE REACTION OF THE ENOLATE [(ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]-LI+ WITH MONOSUBSTITUTED EPOXIDES - X-RAY CRYSTAL-STRUCTURE OF (RS,SR)-[(ETA-5-C5H5)FE(CO)(PPH3)(COCH2CH2CH(OH)ME)]
حسب: Brown, S, وآخرون
منشور في: (1985)

CONFORMATIONAL-ANALYSIS AND DYNAMICS OF THE TRIPHENYLPHOSPHINE LIGAND IN [(ETA-5-C5H5)FE(CO)(PPH3)COCH3]
حسب: Davies, S, وآخرون
منشور في: (1991)

STEREOSELECTIVE CARBON CARBON BOND FORMATION VIA ALKYLATION OF [(ETA-5-C5H5)FE(PPH3)(CO)(COME=CHR)] (R=ME,PRN,PH) - X-RAY CRYSTAL-STRUCTURE OF (Z)-[(ETA-5-C5H5)FE(PPH3)(CO)(COME=CHME)]
حسب: Baird, G, وآخرون
منشور في: (1984)

ELABORATION OF ACYL LIGANDS - PREPARATION AND REACTIVITY OF THE ANION [ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]-
حسب: Aktogu, N, وآخرون
منشور في: (1984)

SELF-RECOGNITION BY THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] IN THE FORMATION OF (RR,SS)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2]2CH2
حسب: Bodwell, G, وآخرون
منشور في: (1991)

ASYMMETRIC DIELS-ALDER REACTIONS - (S)-(+)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CH2] AS A CHIRAL ACRYLATE DIENOPHILE EQUIVALENT
حسب: Davies, S, وآخرون
منشور في: (1986)

A NOVEL ONE-POT SYNTHESIS OF HOMOCHIRAL (R)-(-) AND (S)-(+)-FE(CO)(ETA(5)-C5H5)(PPH(3))COCH3
حسب: Cook, S, وآخرون
منشور في: (1994)

STEREOSELECTIVE ELABORATION OF THE ACYL LIGAND IN (ETA-5-C5H5)FE(CO)(PPH3)(COCH2R) VIA THE ALKYLATION OF THE ANIONS "[(ETA-5-C5H5)FE(CO)(PPH3)(COCHR)]LI (R = ME, ET)
حسب: Baird, G, وآخرون
منشور في: (1983)

CHIRAL DIENOLATES - STEREOSELECTIVE FORMATION AND ALPHA-ALKYLATION OF THE LITHIUM DIENOLATES DERIVED FROM (RS)-Z-[(ETA5-C5H5)FE(CO)(PPH3)COCH=CHCH2R] (R=ME,ET,N-PR) AND (RS)-[(ETA5-C5H5)FE(CO)(PPH3)(COCH=CME2)]
حسب: Davies, S, وآخرون
منشور في: (1986)

CHIRAL RECOGNITION IN THE MICHAEL ADDITION-REACTION BETWEEN LITHIUM N-3,4-DIMETHOXYBENZYL-ALPHA-METHYLBENZYLAMIDE AND THE CHIRAL IRON CROTONOYL COMPLEX [(C5H5)FE(CO)(PPH3)(COCH=CHME)]
حسب: Davies, S, وآخرون
منشور في: (1990)

ASYMMETRIC-SYNTHESIS OF PHENYL ALKYL SULFOXIDES VIA THE NON-DESTRUCTIVE MEDIATION OF THE CHIRAL IRON ACYL[(ETA-5-C5H5)FE(CO)(PPH3)COCH2ME]
حسب: Davies, S, وآخرون
منشور في: (1988)

STEREOSELECTIVE ADDITIONS TO THE ALKOXYCARBENE CATIONS [ETA-5-C5H5)FE(CO)(PPH3)(=CHOME)], [ETA-5-C5H5)FE(CO)(PPH3)(=CETOME)]
حسب: Baird, G, وآخرون
منشور في: (1984)

STEREOSPECIFICITY OF THE REARRANGEMENT OF THE ALPHA-ALKOXY IRON ACYL [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] TO THE ALPHA-METALLA-ESTER [(ETA-5-C5H5)FE(CO)(PPH3)CH2CO2CH2PH]
حسب: Davies, S, وآخرون
منشور في: (1987)

ASYMMETRIC-SYNTHESIS OF (1R,8S)-1-HYDROXYPYRROLIZIDIN-3-ONES AND (1S,8S)-1-HYDROXYPYRROLIZIDIN-3-ONES VIA THE ALDOL REACTION BETWEEN N-BOC-(S)-PROLINAL AND CHIRAL ACETATE ENOLATE EQUIVALENTS DERIVED FROM (S)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH3] AND (R)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH3]
حسب: Beckett, R, وآخرون
منشور في: (1992)

ASYMMETRIC-SYNTHESIS OF (S)-(-)-METHYL TROPINATE - APPLICATION OF THE IRON ACYL COMPLEX (S)-(+)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2PH] AS A HOMOCHIRAL PHENYLACETATE ENOLATE EQUIVALENT
حسب: Baker, T, وآخرون
منشور في: (1993)

RESOLUTION OF THE CHIRAL IRON ACETYL COMPLEX [(C5H5)FE(CO)(PPH3)COCH3]
حسب: Baker, R, وآخرون
منشور في: (1993)

ASYMMETRIC-SYNTHESIS VIA THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
حسب: Davies, S
منشور في: (1988)

CONFORMATIONAL-ANALYSIS OF THE IRON ACETYL COMPLEX [(N5-C5H5)FE(CO)(PPH3)COCH3]
حسب: Davies, S, وآخرون
منشور في: (1986)

CHIRAL ACETATE ENOLATE EQUIVALENT FOR THE SYNTHESIS OF BETA-HYDROXY ACIDS AND ESTERS - X-RAY CRYSTAL-STRUCTURE OF RR,SS-[ETA-5-C5H5)FE(CO)(PPH3)(COCH2CH(OH)CH2CH3)
حسب: Davies, S, وآخرون
منشور في: (1985)

THE ASYMMETRIC SYNTHESIS OF (-)-ACTINONIN USING THE IRON CHIRAL AUXILIARY [(ETA5-C5H5)FE(CO)(PPH3)]
حسب: Bashiardes, G, وآخرون
منشور في: (1988)

THE ASYMMETRIC-SYNTHESIS OF (-)-CAPTOPRIL UTILIZING THE IRON CHIRAL AUXILIARY [ETA-5-C5H5)FE(CO)(PPH3)]
حسب: Bashiardes, G, وآخرون
منشور في: (1987)

CHIRAL RECOGNITION IN THE REACTION OF THE ENOLATE DERIVED FROM [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] WITH 1-PHENYLETHYL BROMIDE
حسب: Davies, S, وآخرون
منشور في: (1990)

CHIRAL RECOGNITION IN THE SN2 REACTION OF TERT-BUTYL 2-BROMOPROPIONATE WITH THE ENOLATE DERIVED FROM [(ETA-5-C5H5)FE(CO)(PPH3)COCH3]
حسب: Collingwood, S, وآخرون
منشور في: (1990)

CONFORMATION ANALYSIS OF COMPOUNDS OF THE TYPE [FE(ETA-5-C5H5)(CO)(PPH3)(CH2ALKYL)], "[FE(ETA-5-C5H5)(CO)(PPH3)(CH2ARYL)] - REPLY
حسب: Seeman, J, وآخرون
منشور في: (1985)

CONFORMATIONAL-ANALYSIS FOR THE PSEUDO-OCTAHEDRAL COMPLEXES - [(ETA-5-C5H5)FE(CO)-(PPH3)CH2R
حسب: Blackburn, B, وآخرون
منشور في: (1987)

Stereoselective conjugate addition reactions of lithium amides to alpha,beta-unsaturated chiral iron acyl complexes [(eta(5)-C5H5)Fe(CO)(PPh3)(COCH=CHR)]
حسب: Davies, S, وآخرون
منشور في: (2004)

STEREOSELECTIVE REDUCTION OF (R,S)-[(ETA-5-C5H5)FE(CO)(PPH3)(=COCH2CH2CME2)]+ AND COMPLETE EPIMERIZATION OF THE KINETIC (RR,SS)-DIASTEREOISOMER TO THE THERMODYNAMIC (RS,SR)-DIASTEREOISOMER OF THE PRODUCT [(ETA-5-C5H5)FE(CO)(PPH3)(C(H)OCH2CH2CME2)]
حسب: Ayscough, A, وآخرون
منشور في: (1986)

ASYMMETRIC-SYNTHESIS OF HOMOCHIRAL BETA-LACTONES VIA THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
حسب: Casegreen, S, وآخرون
منشور في: (1991)

STEREOSELECTIVE ALKYLATIONS OF ENOLATES DERIVED FROM LIGANDS ATTACHED TO THE INDENYL IRON CHIRAL AUXILIARY [ETA-5-C9H7)FE(CO)(PPH3)] - X-RAY CRYSTAL-STRUCTURE AND CONFORMATIONAL-ANALYSIS OF [ETA-5-C9H7)FE(CO)(PPH3)COCH3]
حسب: Davies, S, وآخرون
منشور في: (1991)

CONFORMATIONAL-ANALYSIS AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)(PPH3)CH2CH3]
حسب: Davies, S, وآخرون
منشور في: (1987)

CONFORMATIONAL-ANALYSIS AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)PPH3)CH2SIME3]
حسب: Davies, S, وآخرون
منشور في: (1987)

CONFORMATION-REACTIVITY RELATIONSHIPS FOR THE ORGANOTRANSITION-METAL COMPLEXES (ETA-5-C5H5)FE(CO)(PPH3)R AND (ETA-5-C5H5)RE(NO)(PPH3)R (R = ALKYL AND ARYL)
حسب: Seeman, J, وآخرون
منشور في: (1985)

ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS [FE(ETA-5-C5H5)(PHP(CH2CH2PPH2)2)]+, [FE(ETA-5-C5H5)(MEC(CH2PPH2)3)]+, AND [FE(ETA-5-C5H5)(C(CH2PPH2)4)]+
حسب: Davies, S, وآخرون
منشور في: (1983)

THE ASYMMETRIC-SYNTHESIS OF BETA-LACTAMS - STEREOCONTROLLED ASYMMETRIC TANDEM MICHAEL ADDITIONS AND ALKYLATIONS OF ALPHA,BETA-UNSATURATED ACYL LIGANDS BOUND TO THE CHIRAL AUXILIARY [BETA-C5H5)FE(CO)(PPH3)]
حسب: Davies, S, وآخرون
منشور في: (1986)

ASYMMETRIC-SYNTHESIS OF 2,4-DISUBSTITUTED BUTYROLACTONES USING THE IRON CHIRAL AUXILIARY [ETA-5-C5H5)FE(CO)(PPH3)]
حسب: Davies, S, وآخرون
منشور في: (1990)