Exploring the mechanism of the hydroboration of alkenes by amine–boranes catalysed by [Rh(xantphos)]+

<p style="text-align:justify;">The [Rh(xantphos)]+ fragment acts as an effective catalyst for the hydroboration of the alkene TBE (tert-butyl ethene) using the amine–borane H3B·NMe3 at low (0.5 mol%) catalyst loadings to give the linear product. Investigations into the mechanism usi...

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Autors principals: Johnson, H, Torry-Harris, R, Ortega, L, Theron, R, McIndoe, J, Weller, A
Format: Journal article
Idioma:English
Publicat: Royal Society of Chemistry 2014