Negative thermal expansion and low-frequency modes in cyanide-bridged framework materials
We analyze the intrinsic geometric flexibility of framework structures incorporating linear metal-cyanide-metal (M-CN- M′) linkages using a reciprocal-space dynamical matrix approach. We find that this structural motif is capable of imparting a significant negative thermal expansion (NTE) effect upo...
| Główni autorzy: | , |
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| Format: | Journal article |
| Język: | English |
| Wydane: |
2005
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