Electrochemical determination of sulfide at high temperatures via its electrochemically initiated reaction with diethyl-p-phenylenediamine in dimethylformamide

The electrochemical oxidation of DEPD proceeds via an ECrevECE mechanism in dimethylformamide. It has been investigated at elevated temperatures up to 130 °C at both micro and macro platinum and glassy carbon electrodes. Kinetic and thermodynamic parameters for the reaction process have been calcula...

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Détails bibliographiques
Auteurs principaux: Wildgoose, G, Giovanelli, D, Klymenko, O, Lawrence, N, Jiang, L, Jones, T, Compton, R
Format: Journal article
Langue:English
Publié: 2004