Electrochemical determination of sulfide at high temperatures via its electrochemically initiated reaction with diethyl-p-phenylenediamine in dimethylformamide
The electrochemical oxidation of DEPD proceeds via an ECrevECE mechanism in dimethylformamide. It has been investigated at elevated temperatures up to 130 °C at both micro and macro platinum and glassy carbon electrodes. Kinetic and thermodynamic parameters for the reaction process have been calcula...
Main Authors: | Wildgoose, G, Giovanelli, D, Klymenko, O, Lawrence, N, Jiang, L, Jones, T, Compton, R |
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Format: | Journal article |
Language: | English |
Published: |
2004
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