Mechanistic study of arylsilane oxidation through (19)F NMR spectroscopy

The mechanism of the oxidation of arylsilanes to phenols has been investigated using (19)F NMR spectroscopy. The formation of silanols in these reactions results from a rapid background equilibrium between silanol and alkoxysilane; the relative rates of reaction of these species was evaluated by mod...

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Bibliographic Details
Main Authors: Rayment, E, Mekareeya, A, Summerhill, N, Anderson, E
Format: Journal article
Language:English
Published: American Chemical Society 2017