Mechanistic study of arylsilane oxidation through (19)F NMR spectroscopy

The mechanism of the oxidation of arylsilanes to phenols has been investigated using (19)F NMR spectroscopy. The formation of silanols in these reactions results from a rapid background equilibrium between silanol and alkoxysilane; the relative rates of reaction of these species was evaluated by mod...

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Autori principali: Rayment, E, Mekareeya, A, Summerhill, N, Anderson, E
Natura: Journal article
Lingua:English
Pubblicazione: American Chemical Society 2017