Barrierless photoisomerization of 11-cis retinal protonated Schiff base in solution

A hallmark of the primary visual event is the barrierless, ultrafast, and efficient 11-cis to all-trans photoisomerization of the retinal protonated Schiff base (RPSB) chromophore. The remarkable reactivity of RPSB in the visual pigment rhodopsin has been attributed to potential energy surface modif...

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Bibliographic Details
Main Authors: Bassolino, G, Sovdat, T, Soares Duarte, A, Lim, J, Schnedermann, C, Liebel, M, Odell, B, Claridge, T, Fletcher, S, Kukura, P
Format: Journal article
Language:English
Published: American Chemical Society 2015