Crystallization and phase separation in nonadditive binary hard-sphere mixtures
We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the flu...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2000
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