Crystallization and phase separation in nonadditive binary hard-sphere mixtures
We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the flu...
| Main Authors: | , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2000
|
| _version_ | 1826303237846728704 |
|---|---|
| author | Louis, A Finken, R Hansen, J |
| author_facet | Louis, A Finken, R Hansen, J |
| author_sort | Louis, A |
| collection | OXFORD |
| description | We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well. |
| first_indexed | 2024-03-07T05:59:36Z |
| format | Journal article |
| id | oxford-uuid:ebb82d93-141a-4ed1-91c2-4a8e55b915e4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:59:36Z |
| publishDate | 2000 |
| record_format | dspace |
| spelling | oxford-uuid:ebb82d93-141a-4ed1-91c2-4a8e55b915e42022-03-27T11:11:53ZCrystallization and phase separation in nonadditive binary hard-sphere mixturesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ebb82d93-141a-4ed1-91c2-4a8e55b915e4EnglishSymplectic Elements at Oxford2000Louis, AFinken, RHansen, JWe calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well. |
| spellingShingle | Louis, A Finken, R Hansen, J Crystallization and phase separation in nonadditive binary hard-sphere mixtures |
| title | Crystallization and phase separation in nonadditive binary hard-sphere mixtures |
| title_full | Crystallization and phase separation in nonadditive binary hard-sphere mixtures |
| title_fullStr | Crystallization and phase separation in nonadditive binary hard-sphere mixtures |
| title_full_unstemmed | Crystallization and phase separation in nonadditive binary hard-sphere mixtures |
| title_short | Crystallization and phase separation in nonadditive binary hard-sphere mixtures |
| title_sort | crystallization and phase separation in nonadditive binary hard sphere mixtures |
| work_keys_str_mv | AT louisa crystallizationandphaseseparationinnonadditivebinaryhardspheremixtures AT finkenr crystallizationandphaseseparationinnonadditivebinaryhardspheremixtures AT hansenj crystallizationandphaseseparationinnonadditivebinaryhardspheremixtures |