Crystallization and phase separation in nonadditive binary hard-sphere mixtures

We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the flu...

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Những tác giả chính: Louis, A, Finken, R, Hansen, J
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2000
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author Louis, A
Finken, R
Hansen, J
author_facet Louis, A
Finken, R
Hansen, J
author_sort Louis, A
collection OXFORD
description We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.
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spelling oxford-uuid:ebb82d93-141a-4ed1-91c2-4a8e55b915e42022-03-27T11:11:53ZCrystallization and phase separation in nonadditive binary hard-sphere mixturesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ebb82d93-141a-4ed1-91c2-4a8e55b915e4EnglishSymplectic Elements at Oxford2000Louis, AFinken, RHansen, JWe calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.
spellingShingle Louis, A
Finken, R
Hansen, J
Crystallization and phase separation in nonadditive binary hard-sphere mixtures
title Crystallization and phase separation in nonadditive binary hard-sphere mixtures
title_full Crystallization and phase separation in nonadditive binary hard-sphere mixtures
title_fullStr Crystallization and phase separation in nonadditive binary hard-sphere mixtures
title_full_unstemmed Crystallization and phase separation in nonadditive binary hard-sphere mixtures
title_short Crystallization and phase separation in nonadditive binary hard-sphere mixtures
title_sort crystallization and phase separation in nonadditive binary hard sphere mixtures
work_keys_str_mv AT louisa crystallizationandphaseseparationinnonadditivebinaryhardspheremixtures
AT finkenr crystallizationandphaseseparationinnonadditivebinaryhardspheremixtures
AT hansenj crystallizationandphaseseparationinnonadditivebinaryhardspheremixtures