Crystallization and phase separation in nonadditive binary hard-sphere mixtures

We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the flu...

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Autori principali: Louis, A, Finken, R, Hansen, J
Natura: Journal article
Lingua:English
Pubblicazione: 2000