Controlling structure and reactivity in cationic Solid–State Molecular OrganoMetallic (SMOM) systems using anion templating

The role that the supporting anion has on the stability, structure and catalytic performance, in Solid-state Molecular Organ-oMetallic systems (SMOM) based upon [Rh(Cy2PCH2CH2PCy2)(η2η2-NBD)][BArX4], [1-NBD][BArX4], is reported (X = Cl, F, H; NBD = norbornadiene). The tetra–aryl borate anion is syst...

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Bibliographic Details
Main Authors: McKay, A, Martinez-Martinez, A, Griffiths, H, Rees, N, Waters, J, Weller, A, Krämer, T, Macgregor, S
Format: Journal article
Published: American Chemical Society 2018