Electrochemical random-walk theory Probing voltammetry with small numbers of molecules: Stochastic versus statistical (Fickian) diffusion
Electrochemical simulation is employed to investigate voltammetry in solutions of very low concentrations. Using Monte Carlo random-walk simulations, potential-step chronoamperometry is considered from the perspective of individual species under Brownian motion in solution interacting with an electr...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Elsevier
2011
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