Slurry-phase ethylene polymerization using pentafluorophenyl- and pentafluorophenoxy-modified solid polymethylaluminoxanes

Postsynthesis modification of solid polymethylaluminoxane (sMAO) with tris(pentafluorophenyl)borane or pentafluorophenol produces highly active metallocene supports "sMMAOs" for use in slurry-phase ethylene polymerization. Characterization of the sMMAOs using elemental analysis, BET isothe...

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Bibliographic Details
Main Authors: Kilpatrick, A, Rees, N, Sripothongnak, S, Buffet, J, O'Hare, D
Format: Journal article
Published: American Chemical Society 2017