NIOBIUM METALLABORANES - A NOVEL METALLABORANE ANALOG OF PENTABORANE(11)
Treatment of [Nb(η-C5H5)2H3] with pentaborane(9) gives the novel arachno-metallaboranes [Nb(η-C5H5)2B4H9 ] (1) and [Nb(η-C5H5)2B3H8 ] (2). Compound 1 is the first reported base subrogated analogue of the neutral arachno-pentaborane(11) and has an apex to niobium hydrogen bridge. Compound 2, for whic...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1990
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