Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

We describe the thermal rearrangement of aldehydes bearing an α-(allyl- or crotylsilyl)oxy substituent. The transformations are best described mechanistically as intramolecular silatropic ene reactions based on stereoselectivity, kinetic and computed transition state data. The overall process consti...

書誌詳細
主要な著者:	Robertson, J, Hall, M, Green, S
フォーマット:	Journal article
言語:	English
出版事項:	2009

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