Synthesis and structural investigations of bulky imino- and amido-phosphine palladium dimers

The reactions of palladium(II) dimers [Pd2Br2(L1)2] and [Pd2Br2(L2)2] (where L1- is [Ph2PCH{double bond, long}C(Ph)N(2,6-iPr2C6H3)]- and L2- is [Ph2PCH{double bond, long}C(Ph)N(2,6-Me2C6H3)]-) with AgBF4 in a mixture of CH2Cl2 and MeOH give palladium(I) dimers [Pd2(HL1)2][BF4]2 and [Pd2(HL2)2][BF4]2...

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Bibliographic Details
Main Authors: Pascu, S, Anderson, G, Green, M, Green, J, Rees, N, Cowley, A
Format: Journal article
Language:English
Published: 2006