Synthesis and structural investigations of bulky imino- and amido-phosphine palladium dimers
The reactions of palladium(II) dimers [Pd2Br2(L1)2] and [Pd2Br2(L2)2] (where L1- is [Ph2PCH{double bond, long}C(Ph)N(2,6-iPr2C6H3)]- and L2- is [Ph2PCH{double bond, long}C(Ph)N(2,6-Me2C6H3)]-) with AgBF4 in a mixture of CH2Cl2 and MeOH give palladium(I) dimers [Pd2(HL1)2][BF4]2 and [Pd2(HL2)2][BF4]2...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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