Enantioselectivity in the boron aldol reactions of methyl ketones.

DFT computed transition states quantitatively explain the surprising stereochemical outcome of unsubstituted enolborinates in diastereoselective and enantioselective boron aldol reactions.

Bibliografische gegevens
Hoofdauteurs: Goodman, J, Paton, R
Formaat: Journal article
Taal:English
Gepubliceerd in: Royal Society of Chemistry 2007
Omschrijving
Samenvatting:DFT computed transition states quantitatively explain the surprising stereochemical outcome of unsubstituted enolborinates in diastereoselective and enantioselective boron aldol reactions.