Enantioselectivity in the boron aldol reactions of methyl ketones.

DFT computed transition states quantitatively explain the surprising stereochemical outcome of unsubstituted enolborinates in diastereoselective and enantioselective boron aldol reactions.

Bibliografske podrobnosti
Main Authors: Goodman, J, Paton, R
Format: Journal article
Jezik:English
Izdano: Royal Society of Chemistry 2007
Opis
Izvleček:DFT computed transition states quantitatively explain the surprising stereochemical outcome of unsubstituted enolborinates in diastereoselective and enantioselective boron aldol reactions.