Synthesis of polyyne rotaxanes.

Synthesis of polyyne rotaxanes.

Active-metal templating has been used to synthesize rotaxanes consisting of a phenanthroline-based macrocycle threaded around a C8, C12, or C20 polyyne chain. The crystal structure of the C12 rotaxane has been determined. In the rhenium(I) carbonyl complex of this rotaxane, with Re(CO)(3)Cl coordina...

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Bibliographic Details
Main Authors:	Movsisyan, L, Kondratuk, D, Franz, M, Thompson, A, Tykwinski, R, Anderson, H
Format:	Journal article
Language:	English
Published:	2012

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