Reactivity of Tetrel-Functionalized Heptaphosphane Clusters toward Azides

In this work, the reactivity of tetrel-functionalized phosphorus clusters toward organoazides is probed. Clusters (Me3Si)3P7 (1) and (Me3Ge)3P7 (2) were reacted with benzyl azide, phenyl azide, and 4-bromophenyl azide, and it was found that the [RN] (R = benzyl, phenyl, and 4-bromophenyl) unit from...

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Bibliographic Details
Main Authors: Jobbins, WD, Cullen, RT, Stott, T, van IJzendoorn, B, Réant, BLL, Johnstone, TC, Mehta, M
Format: Journal article
Language:English
Published: American Chemical Society 2024