Reactivity of Tetrel-Functionalized Heptaphosphane Clusters toward Azides

Reactivity of Tetrel-Functionalized Heptaphosphane Clusters toward Azides

In this work, the reactivity of tetrel-functionalized phosphorus clusters toward organoazides is probed. Clusters (Me3Si)3P7 (1) and (Me3Ge)3P7 (2) were reacted with benzyl azide, phenyl azide, and 4-bromophenyl azide, and it was found that the [RN] (R = benzyl, phenyl, and 4-bromophenyl) unit from...

Полное описание

Библиографические подробности
Главные авторы:	Jobbins, WD, Cullen, RT, Stott, T, van IJzendoorn, B, Réant, BLL, Johnstone, TC, Mehta, M
Формат:	Journal article
Язык:	English
Опубликовано:	American Chemical Society 2024

Схожие документы

Nonlinear Optical Response of Tetrel-Modified Tetraphenyl-Adamantane Clusters
по: Ferdinand Ziese, и др.
Опубликовано: (2024-12-01)

The Tetrel Bonds of Hypervalent Halogen Compounds
по: Zhihao Niu, и др.
Опубликовано: (2023-10-01)

On the Power of Geometry over Tetrel Bonds
по: Ephrath Solel, и др.
Опубликовано: (2018-10-01)

Electronic structure of clusters of tetrel elements containing endohedral transition metal ions
по: Jin, X
Опубликовано: (2018)

Transforming carbon dioxide into a methanol surrogate using modular transition metal-free Zintl ions
по: van IJzendoorn, B, и др.
Опубликовано: (2024)

Tetrel Interactions from an Interacting Quantum Atoms Perspective
по: José Luis Casals-Sainz, и др.
Опубликовано: (2019-06-01)

Strong Tetrel Bonds: Theoretical Aspects and Experimental Evidence
по: Mehdi D. Esrafili, и др.
Опубликовано: (2018-10-01)

π-Hole Tetrel Bonds—Lewis Acid Properties of Metallylenes
по: Sławomir J. Grabowski
Опубликовано: (2022-01-01)

Tetrel Bonding in Anion Recognition: A First Principles Investigation
по: Pradeep R. Varadwaj
Опубликовано: (2022-12-01)

Tetrel Bonding as a Vehicle for Strong and Selective Anion Binding
по: Steve Scheiner
Опубликовано: (2018-05-01)

THE VACANCY CLUSTER IN THREADED CRYSTALS OF SILVER AZIDE
по: L.V. Kuzmina, и др.
Опубликовано: (2013-11-01)

Crystallographic and Computational Characterization of Methyl Tetrel Bonding in S-Adenosylmethionine-Dependent Methyltransferases
по: Raymond C. Trievel, и др.
Опубликовано: (2018-11-01)

Comparative Strengths of Tetrel, Pnicogen, Chalcogen, and Halogen Bonds and Contributing Factors
по: Wenbo Dong, и др.
Опубликовано: (2018-07-01)

Differential Binding of Tetrel-Bonding Bipodal Receptors to Monatomic and Polyatomic Anions
по: Steve Scheiner
Опубликовано: (2019-01-01)

Comparison for Electron Donor Capability of Carbon-Bound Halogens in Tetrel Bonds
по: Qingqing Yang, и др.
Опубликовано: (2021-10-01)

Reactive & Efficient: Organic Azides as Cross-Linkers in Material Sciences
по: Marvin Schock, и др.
Опубликовано: (2020-02-01)

Tetrel bond in the triphenyltin(IV) chloride–cyclohexyldiphenylphosphane oxide (1/1) cocrystal
по: Sachin Liyanage, и др.
Опубликовано: (2023-08-01)

Cooperative Effects in Weak Interactions: Enhancement of Tetrel Bonds by Intramolecular Hydrogen Bonds
по: Cristina Trujillo, и др.
Опубликовано: (2019-01-01)

Comparison between Tetrel Bonded Complexes Stabilized by σ and π Hole Interactions
по: Wiktor Zierkiewicz, и др.
Опубликовано: (2018-06-01)

New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway
по: Andrei Dascalu, и др.
Опубликовано: (2014-10-01)

Tetrel Bonds between Phenyltrifluorosilane and Dimethyl Sulfoxide: Influence of Basis Sets, Substitution and Competition
по: Xiulin An, и др.
Опубликовано: (2021-11-01)

Tetrel Bonding Interactions Involving Carbon at Work: Recent Advances in Crystal Engineering and Catalysis
по: Antonio Frontera
Опубликовано: (2020-09-01)

Noncovalent chalcogen and tetrel bonding interactions: Spectroscopic study of halide–carbonyl sulfide complexes
по: Christian T. Haakansson, и др.
Опубликовано: (2023-04-01)

Substituent Effects in Tetrel Bonds Involving Aromatic Silane Derivatives: An ab initio Study
по: Sergi Burguera, и др.
Опубликовано: (2023-03-01)

Lewis Acid Properties of Tetrel Tetrafluorides—The Coincidence of the σ-Hole Concept with the QTAIM Approach
по: Sławomir J. Grabowski
Опубликовано: (2017-02-01)

Tetrel Bonding Interactions in Perchlorinated Cyclopenta- and Cyclohexatetrelanes: A Combined DFT and CSD Study
по: Antonio Bauzá, и др.
Опубликовано: (2018-07-01)

Complexes of CO2 with the Azoles: Tetrel Bonds, Hydrogen Bonds and Other Secondary Interactions
по: Janet E. Del Bene, и др.
Опубликовано: (2018-04-01)

Towards an Asymmetric Organocatalytic α-Azidation of β-Ketoesters
по: Maximilian Tiffner, и др.
Опубликовано: (2018-05-01)

Towards the Synthesis of Graphene Azide from Graphene Oxide
по: Christian E. Halbig, и др.
Опубликовано: (2015-11-01)

Metal‐free fast azidation by using tetrabutylammonium azide : effective synthesis of alkyl azides and well‐defined azido‐end polymethacrylates
по: Wang, Chen-Gang, и др.
Опубликовано: (2020)

Azidation in the Difunctionalization of Olefins
по: Kai Wu, и др.
Опубликовано: (2016-03-01)

Synthesis of β-difluoroalkyl azides via elusive 1,2-azide migration
по: Ning, y, и др.
Опубликовано: (2019)

Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 1—Azides, Porphyrins and Corroles
по: Ana R. L. Araújo, и др.
Опубликовано: (2020-04-01)

Radiofluorination of an Anionic, Azide-Functionalized Teroligomer by Copper-Catalyzed Azide-Alkyne Cycloaddition
по: Barbara Wenzel, и др.
Опубликовано: (2023-07-01)

A Combined Experimental/Quantum-Chemical Study of Tetrel, Pnictogen, and Chalcogen Bonds of Linear Triatomic Molecules
по: Freija De Vleeschouwer, и др.
Опубликовано: (2021-11-01)

Identification of the Tetrel Bonds between Halide Anions and Carbon Atom of Methyl Groups Using Electronic Criterion
по: Ekaterina Bartashevich, и др.
Опубликовано: (2019-03-01)

Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
по: Ana R. L. Araújo, и др.
Опубликовано: (2020-04-01)

Crystal Structure of 2-Ethylimidazole-1-sulfonyl Azide: A New Azidation Reagent
по: Herwig Schottenberger, и др.
Опубликовано: (2012-03-01)

Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
по: Nuligonda Thirupathi, и др.
Опубликовано: (2019-07-01)

Some aspects of azide reactions
по: Seager, J, и др.
Опубликовано: (1973)