Rhodium-catalyzed reductive aldol reactions using aldehydes as the stoichiometric reductants.
Chelated acyl rhodium hydrides, generated from the addition of [Rh(dppe)]ClO4 to beta-sulfide-substituted aldehydes, can function as the stoichiometric reductants in reductive aldol processes. Unsaturated nitriles, esters, and ketones can be used as enolate equivalents, and a variety of simple alpha...
| Autors principals: | , |
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| Format: | Journal article |
| Idioma: | English |
| Publicat: |
2005
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