Synthesis of tetrahydropyrans from sugar lactones

Dehydration of both γ- and δ- hexonolactones, either by intramolecular nucleophilic displacement of triflate leaving groups at C-2, or by Mitsunobu type displacement of the OH-6, provides access to bicyclic lactones which contain tetrahydropyran rings. Reduction or nucleophilic ring opening of these...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Estevez, J, Fairbanks, A, Fleet, G
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 1998