Intramolecular cyclopropanation of epichlorohydrin-derived unsaturated chlorohydrins

Concise stereoselective syntheses of bicyclo[3.1.0]hexan-2-ols and a bicyclo[4.1.0]heptan-2-ol are achieved via regioselective ring-opening of epichlorohydrin with allylic and homoallylic Grignard reagents, followed by lithium 2,2,6,6-tetramethylpiperidide-induced intramolecular cyclopropanation of...

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Những tác giả chính: Hodgson, D, Chung, Y, Paris, J
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2005