Conformational instability of rodlike polyelectrolytes due to counterion fluctuations.
The effective elasticity of highly charged stiff polyelectrolytes is studied in the presence of counterions, with and without added salt. The rigid polymer conformations may become unstable due to an effective attraction induced by counterion density fluctuations. Instabilities at the longest, or in...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2002
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