A random-sequential mechanism for nitrite binding and active site reduction in copper-containing nitrite reductase.

The homotrimeric copper-containing nitrite reductase (NiR) contains one type-1 and one type-2 copper center per monomer. Electrons enter through the type-1 site and are shuttled to the type-2 site where nitrite is reduced to nitric oxide. To investigate the catalytic mechanism of NiR the effects of...

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Bibliographic Details
Main Authors: Wijma, H, Jeuken, L, Verbeet, M, Armstrong, F, Canters, G
Format: Journal article
Language:English
Published: 2006