The interaction of gold(I) cations with 1,3-dienes.
Slip-sliding away: Gold(I) cations bind to only one double bond of a 1,3-diene unit but can glide over the C 4 backbone on a low-activation-energy pathway. However, the binding mode is influenced by substituents on the diene backbone, which also induces a significantly higher...
Main Authors: | , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
2011
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