The interaction of gold(I) cations with 1,3-dienes.
Slip-sliding away: Gold(I) cations bind to only one double bond of a 1,3-diene unit but can glide over the C 4 backbone on a low-activation-energy pathway. However, the binding mode is influenced by substituents on the diene backbone, which also induces a significantly higher...
| Autori principali: | , , , , , |
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| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
2011
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| _version_ | 1826304341418442752 |
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| author | Sanguramath, R Hooper, T Butts, C Green, M McGrady, J Russell, C |
| author_facet | Sanguramath, R Hooper, T Butts, C Green, M McGrady, J Russell, C |
| author_sort | Sanguramath, R |
| collection | OXFORD |
| description | Slip-sliding away: Gold(I) cations bind to only one double bond of a 1,3-diene unit but can glide over the C 4 backbone on a low-activation-energy pathway. However, the binding mode is influenced by substituents on the diene backbone, which also induces a significantly higher barrier to migration. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-07T06:16:21Z |
| format | Journal article |
| id | oxford-uuid:f1344c41-2e35-4a85-8429-6080a0c794f8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:16:21Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:f1344c41-2e35-4a85-8429-6080a0c794f82022-03-27T11:54:16ZThe interaction of gold(I) cations with 1,3-dienes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f1344c41-2e35-4a85-8429-6080a0c794f8EnglishSymplectic Elements at Oxford2011Sanguramath, RHooper, TButts, CGreen, MMcGrady, JRussell, CSlip-sliding away: Gold(I) cations bind to only one double bond of a 1,3-diene unit but can glide over the C 4 backbone on a low-activation-energy pathway. However, the binding mode is influenced by substituents on the diene backbone, which also induces a significantly higher barrier to migration. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | Sanguramath, R Hooper, T Butts, C Green, M McGrady, J Russell, C The interaction of gold(I) cations with 1,3-dienes. |
| title | The interaction of gold(I) cations with 1,3-dienes. |
| title_full | The interaction of gold(I) cations with 1,3-dienes. |
| title_fullStr | The interaction of gold(I) cations with 1,3-dienes. |
| title_full_unstemmed | The interaction of gold(I) cations with 1,3-dienes. |
| title_short | The interaction of gold(I) cations with 1,3-dienes. |
| title_sort | interaction of gold i cations with 1 3 dienes |
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