Structure–reactivity correlations in new W(IV) and Nb(IV) silicon-bridged ansa-metallocene hydrides
W(IV) and Nb(IV) derivatives: [W(L1)MeH] (1), [W(L1)MeH] (2) and [W(L1)O] (3), [W(L2)Cl-2](4), [W(L2)H-2](5), [W(L2)H-3][BF4] (6), [Nb(L2)Cl-2](7) and [Nb(L2)(eta(2)-BH4)](8), where L1 = [(eta-C5H4)(2)SiMe2](2-) and L2 = [(eta-C5H3TMS)(2)SiMe2](2-), have been prepared and characterised. The crystal...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Elsevier
2006
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| Subjects: |