Structure–reactivity correlations in new W(IV) and Nb(IV) silicon-bridged ansa-metallocene hydrides

W(IV) and Nb(IV) derivatives: [W(L1)MeH] (1), [W(L1)MeH] (2) and [W(L1)O] (3), [W(L2)Cl-2](4), [W(L2)H-2](5), [W(L2)H-3][BF4] (6), [Nb(L2)Cl-2](7) and [Nb(L2)(eta(2)-BH4)](8), where L1 = [(eta-C5H4)(2)SiMe2](2-) and L2 = [(eta-C5H3TMS)(2)SiMe2](2-), have been prepared and characterised. The crystal...

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Manylion Llyfryddiaeth
Prif Awduron: Conway, S, Green, M, Pascu, S, Peake, H
Fformat: Journal article
Iaith:English
Cyhoeddwyd: Elsevier 2006
Pynciau: