HIGH-PRESSURE PHASE-TRANSITIONS IN THE 6H PEROVSKITES BA3MSB2O9 (M=MG, NI, ZN)

The 6H perovskitesBa3MSb2O9(M =Mg, Ni, Zn)have been subjected to pressures of up to 5.5 GPa. No structural phase transitions were observed in Ba3MgSb2O9. Ba3NiSb2O9 transformed from a phase containing Sb2O9 dimers formed by face-sharing octahedra into a phase containing NiSbO9 dimers. This was confi...

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Bibliographic Details
Main Authors: Battle, P, Jones, C, Lightfoot, P, Strange, R
Format: Journal article
Language:English
Published: 1990