Structural chemistry and electronic properties of the n=3 Ruddlesden-Popper phases Ca4Mn2FeO9.75 and Sr4Mn2FeO9.80

The room-temperature crystal structures of the n = 3 Ruddlesden-Popper phases Ca4Mn2FeO9.75 and Sr4Mn2FeO9.80 have been refined from neutron and X-ray powder diffraction data. Both adopt space group 14/mmm with (a,c) = (Ca, 3.73683(1), 27.0860(1) ̊), (Sr, 3.83393(1), 27.8148(1) ̊). In both compounds...

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Bibliographic Details
Main Authors: Battle, P, Branford, W, Mihut, A, Rosseinsky, M, Singleton, J, Sloan, J, Spring, L, Vente, J
Format: Journal article
Language:English
Published: 1999