Giving physical insight into the Butler-Volmer model of electrode kinetics: Application of asymmetric Marcus-Hush theory to the study of the electroreductions of 2-methyl-2-nitropropane, cyclooctatetraene and europium(III) on mercury microelectrodes

The asymmetric Marcus-Hush (MH) model for electrode kinetics is applied to the kinetic study of the electroreduction of 2-methyl-2-nitropropane in acetonitrile, cyclooctatetraene in dimethylsulfoxide and europium(III) in aqueous solution, using mercury microhemispheres as working electrodes. This ki...

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Main Authors: Henstridge, M, Laborda, E, Wang, Y, Suwatchara, D, Rees, N, Molina, A, Martinez-Ortiz, F, Compton, R
פורמט: Journal article
שפה:English
יצא לאור: 2012