Discovery of dark pH-dependent H+ migration in a [NiFe]-hydrogenase and its mechanistic relevance: mobilizing the hydrido ligand of the Ni-C intermediate
<p>Despite extensive studies on [NiFe]-hydrogenases, the mechanism by which these enzymes produce and activate H<sub>2</sub> so efficiently remains unclear. A well-known EPR-active state produced under H<sub>2</sub> and known as Ni-C is assigned as a N...
| Main Authors: | , , , , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
American Chemical Society
2015
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