Carbonyl analogues? Analysis of Fe-E (E=B, Al, Ga) bonding in cationic terminal diyl complexes by density functional theory.
A series of DFT calculations has been carried out with the aim of characterizing the metal-group 13 element interaction in the novel cationic borylene complex [(eta5-C2Me5)Fe(CO)2(BMes)]+ (1) and related species of the type [eta5-C5R5)M(L)2(EX)]n+. In addition, comparisons have been made with charge...
मुख्य लेखकों: | Aldridge, S, Rossin, A, Coombs, D, Willock, D |
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स्वरूप: | Journal article |
भाषा: | English |
प्रकाशित: |
2004
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समान संसाधन
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Fe=B double bonds: Synthetic, structural, and reaction chemistry of cationic terminal borylene complexes
द्वारा: Coombs, D, और अन्य
प्रकाशित: (2004) -
Cationic terminal borylenes by halide abstraction: synthesis and spectroscopic and structural characterization of an Fe=B double bond.
द्वारा: Coombs, D, और अन्य
प्रकाशित: (2003) -
Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.
द्वारा: Bunn, N, और अन्य
प्रकाशित: (2004) -
Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.
द्वारा: Aldridge, S, और अन्य
प्रकाशित: (2006) -
Cationic terminal aminoborylene complexes: controlled stepwise insertion into M=B and B=N double bonds.
द्वारा: Pierce, G, और अन्य
प्रकाशित: (2007)