WATER-SOLUBLE, ZERO-VALENT, PLATINUM-P(CH2OH)3 PALLADIUM-P(CH2OH)3 AND NICKEL-P(CH2OH)3 COMPLEXES - CATALYSTS FOR THE ADDITION OF PH3 TO CH2O
The phosphine P(CH2OH)3 forms water soluble complexes of the type[M{P(CH2OH)3}4] (M = pt, Pd, or Ni) which are catalysts for the addition of PH3 to CH2O and the Pt complex is readily protonated by water;the crystal structure of the Pd complex is also described.
Main Authors: | , , , , |
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Format: | Journal article |
Language: | English |
Published: |
1989
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