Competition between Anion-Deficient Oxide and Oxyhydride Phases during the Topochemical Reduction of LaSrCoRuO 6

Binary metal hydrides can act as low-temperature reducing agents for complex oxides in the solid state, facilitating the synthesis of anion-deficient oxide or oxyhydride phases. The reaction of LaSrCoRuO6, with CaH2 in a sealed tube yields the face-centered cubic phase LaSrCoRuO3.2H1.9. The reaction...

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Bibliographic Details
Main Authors: Liang, Z, Batuk, M, Orlandi, F, Manuel, P, Hadermann, J, Hayward, MA
Format: Journal article
Language:English
Published: American Chemical Society 2024